From mboxrd@z Thu Jan  1 00:00:00 1970
From: John Kitchin <jkitchin@andrew.cmu.edu>
Subject: Re: Bibliograph:ref.bib vs. \printbibliograpy (WAS: Re: > Citations
 with org-ref in apa style)
Date: Sun, 18 Jun 2017 16:38:05 -0400
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Try this to get the heading you want. It seems to work for me.

# https://tex.stackexchange.com/questions/17445/how-can-i-change-the-references-to-reference-in-the-thebibliography-environm
# This makes the bibliography section title empty and un-numbered
#+latex: \renewcommand{\bibsection}{\subsection*{}}

* References
bibliographystyle:unsrt
bibliography:References.bib

>
> * I want this to say "References"
>    I don't need this to say References again:
>    bibliographystyle:unsrt
>    bibliography:References.bib
> =================================
>
> References.bib
> =================================
> @article{SmartGuy17,
>    author =       {A. Smart and Handsome Guy},
>    title =        {Enjoying Emacs and Org-mode},
>    journal =      {Hacking Accounts of Freedom},
>    volume =       {2},
>    number =       {4},
>    pages =        {1858-1894},
>    year =         {2017},
> }
> =================================
>
> I hope that this helps :) . Good hacking!
>
> Org mode version 9.0.7
> GNU Emacs 24.4.1
> org-ref: Version 0.9.0
>
> -------------------------------------------------
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--
Professor John Kitchin
Doherty Hall A207F
Department of Chemical Engineering
Carnegie Mellon University
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@johnkitchin
http://kitchingroup.cheme.cmu.edu