The following lines of my '~/.Xmodmap' file remap my left Win key
to Ctrl:

remove mod4 = Super_L
add control = Super_L

When I run GUI Emacs with this in place, entering any keybinding 'C-s-X
is undefined', where X is the key that I pressed. E.g. if I press 'C-n',
I get the following:

'C-s-n is undefined'

In GNU Emacs 29.1 (build 1, x86_64-pc-linux-gnu, GTK+ Version 3.24.38,
cairo version 1.17.8)
Windowing system distributor 'The X.Org Foundation', version 11.0.12101008
System Description: Arch Linux

Configured using:
 'configure --sysconfdir=/etc --prefix=/usr --libexecdir=/usr/lib
 --with-tree-sitter --localstatedir=/var --with-cairo
 --disable-build-details --with-harfbuzz --with-libsystemd
 --with-modules --with-x-toolkit=gtk3 'CFLAGS=-march=x86-64
 -mtune=generic -O2 -pipe -fno-plt -fexceptions -Wp,-D_FORTIFY_SOURCE=2
 -Wformat -Werror=format-security -fstack-clash-protection
 -fcf-protection -g
 -ffile-prefix-map=/build/emacs/src=/usr/src/debug/emacs -flto=auto'
 'LDFLAGS=-Wl,-O1,--sort-common,--as-needed,-z,relro,-z,now -flto=auto''

Configured features:
ACL CAIRO DBUS FREETYPE GIF GLIB GMP GNUTLS GPM GSETTINGS HARFBUZZ JPEG
JSON LCMS2 LIBOTF LIBSYSTEMD LIBXML2 M17N_FLT MODULES NOTIFY INOTIFY
PDUMPER PNG RSVG SECCOMP SOUND SQLITE3 THREADS TIFF TOOLKIT_SCROLL_BARS
TREE_SITTER WEBP X11 XDBE XIM XINPUT2 XPM GTK3 ZLIB

Important settings:
  value of $LANG: C.UTF-8
  locale-coding-system: utf-8-unix

Major mode: Lisp Interaction

Minor modes in effect:
  tooltip-mode: t
  global-eldoc-mode: t
  eldoc-mode: t
  show-paren-mode: t
  electric-indent-mode: t
  mouse-wheel-mode: t
  tool-bar-mode: t
  menu-bar-mode: t
  file-name-shadow-mode: t
  global-font-lock-mode: t
  font-lock-mode: t
  blink-cursor-mode: t
  line-number-mode: t
  indent-tabs-mode: t
  transient-mark-mode: t
  auto-composition-mode: t
  auto-encryption-mode: t
  auto-compression-mode: t

Load-path shadows:
None found.

Features:
(shadow sort mail-extr emacsbug message mailcap yank-media puny dired
dired-loaddefs rfc822 mml mml-sec password-cache epa derived epg rfc6068
epg-config gnus-util text-property-search time-date subr-x mm-decode
mm-bodies mm-encode mail-parse rfc2231 mailabbrev gmm-utils mailheader
cl-loaddefs cl-lib sendmail rfc2047 rfc2045 ietf-drums mm-util
mail-prsvr mail-utils rmc iso-transl tooltip cconv eldoc paren electric
uniquify ediff-hook vc-hooks lisp-float-type elisp-mode mwheel
term/x-win x-win term/common-win x-dnd tool-bar dnd fontset image
regexp-opt fringe tabulated-list replace newcomment text-mode lisp-mode
prog-mode register page tab-bar menu-bar rfn-eshadow isearch easymenu
timer select scroll-bar mouse jit-lock font-lock syntax font-core
term/tty-colors frame minibuffer nadvice seq simple cl-generic
indonesian philippine cham georgian utf-8-lang misc-lang vietnamese
tibetan thai tai-viet lao korean japanese eucjp-ms cp51932 hebrew greek
romanian slovak czech european ethiopic indian cyrillic chinese
composite emoji-zwj charscript charprop case-table epa-hook
jka-cmpr-hook help abbrev obarray oclosure cl-preloaded button loaddefs
theme-loaddefs faces cus-face macroexp files window text-properties
overlay sha1 md5 base64 format env code-pages mule custom widget keymap
hashtable-print-readable backquote threads dbusbind inotify lcms2
dynamic-setting system-font-setting font-render-setting cairo
move-toolbar gtk x-toolkit xinput2 x multi-tty make-network-process
emacs)

Memory information:
((conses 16 36436 12851)
 (symbols 48 5151 0)
 (strings 32 13179 1298)
 (string-bytes 1 373971)
 (vectors 16 9324)
 (vector-slots 8 148882 13860)
 (floats 8 21 23)
 (intervals 56 234 0)
 (buffers 984 10))