True, looking at the new regexp in emacs the escape characters are highlighted in red, indicating an error. I can verify Mattias' modification still works for me.

I can't properly verify the bracketed version of the warning since I don't get those with my ModelSim, but if I manually type out a warning with brackets it does get highlighted when using re-builder. With Reto's modification on the other hand the bracket warning is not highlighted.

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From: Mattias Engdegård <mattiasengdegard@gmail.com> on behalf of Mattias Engdegård <mattias.engdegard@gmail.com>
Sent: Saturday, April 1, 2023 2:01:19 PM
To: reto@gnu.org <reto@gnu.org>
Cc: Cyril Arnould <cyril.arnould@outlook.com>; Eli Zaretskii <eliz@gnu.org>; friedrich.beckmann@gmx.de <friedrich.beckmann@gmx.de>; 62508@debbugs.gnu.org <62508@debbugs.gnu.org>
Subject: bug#62508: 28.2; vhdl-mode ModelSim compile warnings aren't highlighted
 
The new regexp,

"^\\(ERROR\\|WARNING\\|\\*\\* Error\\|\\*\\* Warning\\)[^:]*:\\( *\[[0-9]\]\\| ([^)]+)\\)? \\([^ \t\n]+\\)(\\([0-9]+\\)):"
                                                                  ^^^^^^^^^

isn't quite right: there are single-escaped square brackets, and the original regexp permitted multiple digits, not just one, between square brackets. The part

  "\[[0-9]\]"

should probably be

  "\\[[0-9]+]"

but the author needs to confirm this.