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From: Jason Rumney <jasonrumney@gmail.com>
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Subject: Re: Problem sending email with gnu emacs v 23
Date: Wed, 11 Jul 2012 05:23:20 -0700 (PDT)
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On Wednesday, 11 July 2012 02:21:12 UTC+8, nvangogh  wrote:

> My ISP uses SMTP server on port 465 and I have verified that the server 
> is up and running by a nmap port scan. I have even inserted IP number 
> rather than address.

Port 465 is with TLS/SSL isn't it? You might have better luck with Emacs 24, which has support for gnutls libraries built in rather than relying on external tools.