start-process normalizes the given PROGRAM path by destructively modifying its contents.
This is problematic if the path variable is reused later on.

Minimal repro:
(let ((path "c:/Windows/System32/clip.exe"))
  (start-process "" nil path)
  path) ; => "c:\\Windows\\System32\\clip.exe"

In GNU Emacs 24.5.1 (i686-pc-mingw32)
 of 2015-04-11 on LEG570
Windowing system distributor `Microsoft Corp.', version 6.3.9600
Configured using:
 `configure --prefix=/c/usr --host=i686-pc-mingw32'

Important settings:
  value of $LANG: DEU
  locale-coding-system: cp1252

Major mode: Lisp Interaction

Minor modes in effect:
  tooltip-mode: t
  electric-indent-mode: t
  mouse-wheel-mode: t
  tool-bar-mode: t
  menu-bar-mode: t
  file-name-shadow-mode: t
  global-font-lock-mode: t
  font-lock-mode: t
  blink-cursor-mode: t
  auto-composition-mode: t
  auto-encryption-mode: t
  auto-compression-mode: t
  line-number-mode: t
  transient-mark-mode: t

Recent messages:
For information about GNU Emacs and the GNU system, type C-h C-a.

Load-path shadows:
None found.

Features:
(shadow sort gnus-util mail-extr emacsbug message format-spec rfc822 mml
easymenu mml-sec mm-decode mm-bodies mm-encode mail-parse rfc2231
mailabbrev gmm-utils mailheader sendmail rfc2047 rfc2045 ietf-drums
mm-util help-fns mail-prsvr mail-utils time-date tooltip electric
uniquify ediff-hook vc-hooks lisp-float-type mwheel dos-w32 ls-lisp
w32-common-fns disp-table w32-win w32-vars tool-bar dnd fontset image
regexp-opt fringe tabulated-list newcomment lisp-mode prog-mode register
page menu-bar rfn-eshadow timer select scroll-bar mouse jit-lock
font-lock syntax facemenu font-core frame cham georgian utf-8-lang
misc-lang vietnamese tibetan thai tai-viet lao korean japanese hebrew
greek romanian slovak czech european ethiopic indian cyrillic chinese
case-table epa-hook jka-cmpr-hook help simple abbrev minibuffer nadvice
loaddefs button faces cus-face macroexp files text-properties overlay
sha1 md5 base64 format env code-pages mule custom widget
hashtable-print-readable backquote make-network-process w32notify w32
multi-tty emacs)

Memory information:
((conses 8 73857 5808)
 (symbols 32 17432 0)
 (miscs 32 33 131)
 (strings 16 10612 4319)
 (string-bytes 1 268415)
 (vectors 8 9520)
 (vector-slots 4 383153 5554)
 (floats 8 57 68)
 (intervals 28 196 45)
 (buffers 508 11))